SPHINO-2-PHENYL-1,2-DICARBA-CLOSO-DODECABORANE(12)

Citation
R. Sillanpaa et al., SPHINO-2-PHENYL-1,2-DICARBA-CLOSO-DODECABORANE(12), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2223-2225
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
9
Pages
2223 - 2225
Database
ISI
SICI code
0108-2701(1996)52:<2223:S>2.0.ZU;2-H
Abstract
In the title compound, C14H29B10P, the diisopropylphosphine and phenyl groups are bonded to the C atoms of the 1,2-dicarbadodecaborane cage. Bond lengths are P-C-cage 1.879 (3), P-Ci(Pr) 1.866 (4) and 1.881 (4) , and C-cage-C-cage 1.769 (4) Angstrom. The elongation of the C-cage-C -cage bond is discussed.