ESTERIFICATION OF PHOSPHONIC AND PHOSPHINIC ACID ANALOGS OF GLUTAMIC AND ASPARTIC ACIDS WITH ETHYL ORTHOFORMATE - SCOPE AND LIMITATIONS OF THE METHOD

Citation
E. Zymanczykduda et al., ESTERIFICATION OF PHOSPHONIC AND PHOSPHINIC ACID ANALOGS OF GLUTAMIC AND ASPARTIC ACIDS WITH ETHYL ORTHOFORMATE - SCOPE AND LIMITATIONS OF THE METHOD, Phosphorus, sulfur and silicon and the related elements, 112(1-4), 1996, pp. 47-55
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
112
Issue
1-4
Year of publication
1996
Pages
47 - 55
Database
ISI
SICI code
1042-6507(1996)112:1-4<47:EOPAPA>2.0.ZU;2-Z
Abstract
Reaction of C-ethyl esters of phosphonic- and phosphinic acid analogue s of glutamic and aspartic acids with ethyl orthoformate provides the mixtures of N-formylamino- and N-ethoxymethyleneimino-derivatives with nearly quantitative yields. Scape and limitations of this procedure w ere studied by means of GC/MS technique.