REACTIONS OF THIOXO COMPOUNDS WITH N-CHLO ROAMIDES .7. ,5-DIMETHYL-3-DIMETHYLAMINO-2-CYCLOHEXENE-1-THIONE AND 3-DIMETHYLAMINO-1-PHENYL-2-PROPENE-1-THIONE WITH SODIUM N-CHLOROBENZENESULFONAMIDES

Authors
BOBERG F OTTEN A
Citation
F. Boberg et A. Otten, REACTIONS OF THIOXO COMPOUNDS WITH N-CHLO ROAMIDES .7. ,5-DIMETHYL-3-DIMETHYLAMINO-2-CYCLOHEXENE-1-THIONE AND 3-DIMETHYLAMINO-1-PHENYL-2-PROPENE-1-THIONE WITH SODIUM N-CHLOROBENZENESULFONAMIDES, Phosphorus, sulfur and silicon and the related elements, 112(1-4), 1996, pp. 91-99
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
112
Issue
1-4
Year of publication
1996
Pages
91 - 99
Database
ISI
SICI code
1042-6507(1996)112:1-4<91:ROTCWN>2.0.ZU;2-V
Abstract
The alkenethiones, mentioned in the title, react with sodium N-chlorob enzenesulfonamides (2) to S-alkenylidene-N-arylsulfonylsulfimides (6, 9). Cyclohexenylidenesulfimides 6 are oxidized to dipolar N-(arylsulfo nyl)iminioalkenesulfonamidates (7). Equilibriums between propenylidene sulfimides 9 and dihydrothiazoles (10) are detected in CDCl3 solution by nmr data.