OXIDATION OF 2-SELENOIMIDAZOLINES WITH IO DINE

Authors
KUHN N FAWZI R KRATZ T STEIMANN M HENKEL G
Citation
N. Kuhn et al., OXIDATION OF 2-SELENOIMIDAZOLINES WITH IO DINE, Phosphorus, sulfur and silicon and the related elements, 112(1-4), 1996, pp. 225-233
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
112
Issue
1-4
Year of publication
1996
Pages
225 - 233
Database
ISI
SICI code
1042-6507(1996)112:1-4<225:OO2WID>2.0.ZU;2-J
Abstract
The stepwise oxidation of 2-selenoimidazolines (1) under bar(TmSe; -di hydro-1,3,4,5-tetraalkyl-2H-imidazol-2-ylidene) leads to a series of c arbene stabilised selenium iodine compounds whose composition depend f rom the stoichiometry and the substituents at the nitrogen atoms. No d iselenides or selenium(IV) compounds have been detected. The X-ray str uctures of the compounds [ImSeSeIm](2+) (3c), (ImSeI(2))(2)I-2 (5c) an d (ImSeI)I-3 (6b) are reported.