A NUMERICAL-MODEL FOR THE DISSOLUTION OF SPHERICAL-PARTICLES IN BINARY-ALLOYS UNDER MIXED-MODE CONTROL

Citation
Fj. Vermolen et S. Vanderzwaag, A NUMERICAL-MODEL FOR THE DISSOLUTION OF SPHERICAL-PARTICLES IN BINARY-ALLOYS UNDER MIXED-MODE CONTROL, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 220(1-2), 1996, pp. 140-146
Citations number
8
Categorie Soggetti
Material Science
ISSN journal
09215093
Volume
220
Issue
1-2
Year of publication
1996
Pages
140 - 146
Database
ISI
SICI code
0921-5093(1996)220:1-2<140:ANFTDO>2.0.ZU;2-T
Abstract
A general numerical model is described for the dissolution kinetics of spherical particles in binary systems for any combination of first or der reactions at the particle-matrix interface and long distance diffu sion within the matrix. The model is applicable to both finite and inf inite media and handles both complete and partial particle dissolution . It is shown that interfacial reactions can have a strong effect on t he dissolution kinetics, the solute concentration at the particle-matr ix interface and the solute concentration profile in the matrix.