L. Kerschhofer et al., INTRACRYSTALLINE TRANSFORMATION OF OLIVINE TO WADSLEYITE AND RINGWOODITE UNDER SUBDUCTION ZONE CONDITIONS, Science, 274(5284), 1996, pp. 79-81
Experiments on Mg1.8Fe0.2SiO4 olivine at 18 to 20 gigapascals and 1000
degrees to 1400 degrees C show that transformation to the high-pressu
re polymorphs wadsleyite and ringwoodite involves two competing nuclea
tion mechanisms when the grain size of the olivine is large: (i) incoh
erent nucleation on olivine grain boundaries and (ii) coherent intracr
ystalline nucleation of ringwoodite lamellae on shear-induced stacking
faults in olivine un the (100) planes, followed by the nucleation of
wadsleyite on the ringwoodite. The large amount of Intracrystalline tr
ansformation, which occurs under low differential stress under the pre
ssure and temperature conditions of the mantle transition zone, sugges
ts that shear-induced intracrystalline transformation of olivine to wa
dsleyite and ringwoodite is important in subducting slabs.