N. Kannan et al., REMOVAL OF PHENOLIC-COMPOUNDS BY ELECTROOXIDATION METHOD, Journal of environmental science and health. Part A: Environmental science and engineering, 30(10), 1995, pp. 2185-2203
The present study envisages a method to remove phenol from the phenoli
c effluents by the electrooxidation under alkaline conditons. Syntheti
c effluent containing phenol (100 ppm) is subjected to electrolysis un
der various experimental conditions inorder to find out the optimum co
nditions for the removal of phenol. An electrolysis cell was designed
with graphite electrodes and electrolysis was carried out under galvan
ostatic conditions keeping the total quantity of current at 0.75 A h.
The reduction in concentration of phenol was analysed in terms of COD.
Continuous electrolysis was also carried out at optimum conditions (c
urrent density: 4 A dm(-2), phenol: 100 ppm and supporting electrolyte
. 1M NaOH) to find out the maximum removal of phenol. The removal of p
henol from phenolic effluents is found to be highly efficient to the e
xtent of 98.55%. The electrooxidation of phenol at anode leads to the
formation of carbon di-oxide and water. The study reveals that, the ph
enol can be almost completely oxidised at the graphite anode with a ma
ximum current efficiency of 17%. It is concluded that, the phenol can
be removed from phenolic effluents effectively by electrooxidation met
hod.