Wg. Ellis et al., POTENTIAL OZONE PRODUCTION FOLLOWING CONVECTIVE-TRANSPORT BASED ON FUTURE EMISSION SCENARIOS, Atmospheric environment, 30(4), 1996, pp. 667-672
Current and projected (up to 2050 A.D.) concentrations of boundary lay
er trace gases, including NOx, CO, CH4, and several nonmethane hydroca
rbons were redistributed throughout the troposphere in a simulation of
a central U.S. squall line using the Goddard Cumulus Ensemble (GCE) c
onvective cloud model. Vertical profiles of the redistributed trace ga
ses were used in a one-dimensional photochemical model to determine th
e vertical profile of the potential production of O-3. Several differe
nt emission scenarios were considered. In the case where NOx emissions
were doubled along with an increase in CO, CH4, and NMHC's, the middl
e troposphere showed an enhancement of 41% for O-3 production relative
to the 1985 case. For the reduction scenario, where NOx emissions wer
e decreased by a factor of two, the O-3 produced in the middle troposp
here was reduced by 50%. Given the role of convection in the regional
O-3 budget of the central U.S. during the summertime, our results sugg
est that substantial changes in emissions could bring about changes in
mid-tropospheric O-3 large enough to be observed by satellite remote
sensing.