REACTION OF 1,2-QUINONE MONOOXIMES AND THEIR METAL-COMPLEXES WITH DIMETHYL ACETYLENEDICARBOXYLATE

Authors
BARJESTEH H BRAIN EG CHARALAMBOUS J GAGANATSOU P THOMAS TA
Citation
H. Barjesteh et al., REACTION OF 1,2-QUINONE MONOOXIMES AND THEIR METAL-COMPLEXES WITH DIMETHYL ACETYLENEDICARBOXYLATE, Journal of chemical research. Synopses, (11), 1995, pp. 454
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
11
Year of publication
1995
Database
ISI
SICI code
0308-2342(1995):11<454:RO1MAT>2.0.ZU;2-W
Abstract
1,2-Quinone monooximes (1) and their metal complexes (2) react with di methyl acetylenedicarboxylate (DMAD) under relatively mild conditions to give 1,4-oxazines (3) or 1,4-oxazin-2-ones (4) or the nucleophilic 1,2-addition products (Z)- and (E)-1,2-benzoquinone 1-{O-[1,2-bis(meth oxycarbonyl)ethyenyl]oxime} (5 and 6) or 1,3-oxazoles (7).