G. Foldiak et al., INFLUENCE OF THE RING SIZE ON RADICAL REACTIONS IN RADIOLYSIS OF CYCLOALKANES, Radiation physics and chemistry, 47(3), 1996, pp. 381-383
Citations number
10
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
In the gamma- and 3 MeV alpha-radiolysis of C-5-C-10 cycloalkanes the
slopes of the straight lines obtained by plotting the cycloalkene yiel
ds as a function of the dimer yields were shown to deviate significant
ly from the k(d)/k(c) values determined in radical scavenging experime
nts. This deviation indicates that both the yield of the radical react
ions and the unimolecular cycloalkene formation reaction is dependent
on the type of the radiation.