INFLUENCE OF THE RING SIZE ON RADICAL REACTIONS IN RADIOLYSIS OF CYCLOALKANES

Authors
FOLDIAK G RODER M WOJNAROVITS L
Citation
G. Foldiak et al., INFLUENCE OF THE RING SIZE ON RADICAL REACTIONS IN RADIOLYSIS OF CYCLOALKANES, Radiation physics and chemistry, 47(3), 1996, pp. 381-383
Citations number
10
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Radiation physics and chemistry → ACNP
ISSN journal
0969806X
Volume
47
Issue
3
Year of publication
1996
Pages
381 - 383
Database
ISI
SICI code
0969-806X(1996)47:3<381:IOTRSO>2.0.ZU;2-6
Abstract
In the gamma- and 3 MeV alpha-radiolysis of C-5-C-10 cycloalkanes the slopes of the straight lines obtained by plotting the cycloalkene yiel ds as a function of the dimer yields were shown to deviate significant ly from the k(d)/k(c) values determined in radical scavenging experime nts. This deviation indicates that both the yield of the radical react ions and the unimolecular cycloalkene formation reaction is dependent on the type of the radiation.