HIGH-PRESSURE FREE-RADICAL COPOLYMERIZATION OF ETHENE AND BUTYL ACRYLATE

Authors
BUBACK M BUSCH M LOVIS K MAHLING FO
Citation
M. Buback et al., HIGH-PRESSURE FREE-RADICAL COPOLYMERIZATION OF ETHENE AND BUTYL ACRYLATE, Macromolecular chemistry and physics, 197(1), 1996, pp. 303-313
Citations number
16
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
197
Issue
1
Year of publication
1996
Pages
303 - 313
Database
ISI
SICI code
1022-1352(1996)197:1<303:HFCOEA>2.0.ZU;2-H
Abstract
The free-radical copolymerization of ethene and butyl acrylate was stu died between 130 and 225 degrees C at pressures from 1500 to 2500 bar. The reactions which were induced either thermally or laser-photochemi cally were run in two types of continuously operated devices. Reactivi ty ratio data referring to ethene-rich monomer mixtures are presented. These data allow to estimate the copolymer composition in ethene/buty l acrylate copolymerizations carried out in a wide range of temperatur es and pressures.