The changes in fibre structure caused by the realignment of the microf
ibrils of fibre and yarn samples treated with swelling agents, such as
NaOH, LiOH, ZnCl2, and butyltrimethyl ammonium hydroxide (BTMAH), bot
h under tension and slack, were studied by light and electron microsco
py. The structural effects of treatment of the microfibrils and the ul
timate fibres correlated with the measured variations in fibre tenacit
y and moisture regain. The results of differential thermogravimetric a
nalysis suggested that structural realignment of the cellulosic crysta
ls had taken place during the treatments.