STUDIES ON RELAXATION KINETICS OF COORDIN ATION REACTION BETWEEN TI AND 3,5-DIBROMOSALICYLFLUORONE

Authors
ZHU BX LIN ZX CAI RX
Citation
Bx. Zhu et al., STUDIES ON RELAXATION KINETICS OF COORDIN ATION REACTION BETWEEN TI AND 3,5-DIBROMOSALICYLFLUORONE, Gaodeng xuexiao huaxue xuebao, 17(12), 1996, pp. 1843-1846
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
17
Issue
12
Year of publication
1996
Pages
1843 - 1846
Database
ISI
SICI code
0251-0790(1996)17:12<1843:SORKOC>2.0.ZU;2-3
Abstract
In this paper, the relaxation time was determined at different Ti(IV) concentrations by the concentration jump relaxation method. The reason able mechanism is drawn up. The expression of 1/tau was derived from t he assumed mechanism of reaction. The apparent rate constant and molar absorbance index were obtained by the concentration jump relaxation m ethod. The results shows that the value of stability constant of the c omplex (K = 1.799 X 10(9)) is in agreement with that (K = 2.12 X 10(9) ) obtained by using equilibrium movement method.