ESR INVESTIGATION OF THE PHOSPHORUS-RHENIUM CENTER IN GAMMA-IRRADIATED PHOSPHATE-DOPED AMMONIUM PERRHENATE

Authors
ANUSUYA B MURTY VS RAO KVSR SUBRAMANIAN S
Citation
B. Anusuya et al., ESR INVESTIGATION OF THE PHOSPHORUS-RHENIUM CENTER IN GAMMA-IRRADIATED PHOSPHATE-DOPED AMMONIUM PERRHENATE, Journal of molecular structure, 372(1), 1995, pp. 41-47
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
372
Issue
1
Year of publication
1995
Pages
41 - 47
Database
ISI
SICI code
0022-2860(1995)372:1<41:EIOTPC>2.0.ZU;2-O
Abstract
Single crystals of ammonium perrhenate (NH4ReO4) doped with PO43- and gamma-irradiated at RT (300 K) give rise to paramagnetic centers which could be recorded both at RT and 77 K. The radical has been identifie d as a pseudo V-k center, namely a PO42- radical associated with ReO4- . The g-tensor and the hyperfine A-tenser are found to be axially symm etric and are discussed in detail.