STUDIES ON BIOLOGICAL ACTIVE ORGANOPHOSPH ORUS COMPOUNDS .12. SYNTHESIS AND PROPERTY OF ALPHA-(2-BENZOXAZOLYL)OXYACETOXYALKYL PHOSPHONATES

Authors
HU LM HE HW LIU ZJ
Citation
Lm. Hu et al., STUDIES ON BIOLOGICAL ACTIVE ORGANOPHOSPH ORUS COMPOUNDS .12. SYNTHESIS AND PROPERTY OF ALPHA-(2-BENZOXAZOLYL)OXYACETOXYALKYL PHOSPHONATES, Gaodeng xuexiao huaxue xuebao, 17(12), 1996, pp. 1869-1873
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
17
Issue
12
Year of publication
1996
Pages
1869 - 1873
Database
ISI
SICI code
0251-0790(1996)17:12<1869:SOBAOO>2.0.ZU;2-1
Abstract
Twenty-one new phosphorus compounds were synthesized by the reaction o f O,O-dialkyl-alpha-chloroacetoxyalkyl phosphonates and sodium salt of 3-hydroxymethylbenzoxazolone. Their structures were confirmed by mean s of elementary analysis, IR, H-1 and P-31 NMR and MS. The possible me chanism is that the unsteady reactive intermediate reacting from react ants undergoes intramolecular electron migration rearrangement to form the products.