STEREOSELECTIVE REACTION OF ARYLSULFANYL-STABILIZED HOMOENOLATES WITHALDEHYDES

Authors
SHINOZUKA T KIKORI Y ASAOKA M TAKEI G
Citation
T. Shinozuka et al., STEREOSELECTIVE REACTION OF ARYLSULFANYL-STABILIZED HOMOENOLATES WITHALDEHYDES, Journal of the Chemical Society. Perkin transactions. I, (2), 1996, pp. 119-120
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
2
Year of publication
1996
Pages
119 - 120
Database
ISI
SICI code
0300-922X(1996):2<119:SROAHW>2.0.ZU;2-C
Abstract
The reaction of arylsulfanyl-stabilized lithium homoenolates with arom atic aldehydes gave anti-adducts with a high level of diastereoselecti vity (up to 96% de) and fair enantioselectivity (up to 47% ee) the pre sence of (-)-sparteine.