REACTION OF 5-AMINO-8-HYDROXY-1,4-NAPHTHO QUINONE WITH ALIPHATIC AND AROMATIC-AMINES - THEORETICAL-STUDY OF ITS REACTIVITY AND TAUTOMERIC EQUILIBRIUM

Authors
FRANCESCHINI FC ALONSO FS STEFANI V
Citation
Fc. Franceschini et al., REACTION OF 5-AMINO-8-HYDROXY-1,4-NAPHTHO QUINONE WITH ALIPHATIC AND AROMATIC-AMINES - THEORETICAL-STUDY OF ITS REACTIVITY AND TAUTOMERIC EQUILIBRIUM, Anales de quimica, 91(5-6), 1995, pp. 453-460
Citations number
40
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
91
Issue
5-6
Year of publication
1995
Pages
453 - 460
Database
ISI
SICI code
1130-2283(1995)91:5-6<453:RO5QWA>2.0.ZU;2-2
Abstract
The reaction of 5-amino-8-hydroxy-1,4-naphthoquinone (1) with aliphati c and aromatic amines have been studied, in absence or presence of cop per(II) salts, in order to prepare diaminohydroxy-1,4-naphthoquinones. Also a quantum mechanics calculation on 1 have been done for studing its tautomeric equilibria and rationalizing its behaviour in the react ion with amines.