NEW PREPARATIVE ACCESS TO AND THE CRYSTAL AND MOLECULAR-STRUCTURES OFCIS-[PTCL2(CO)(2)]

Authors
BAGNOLI F DELLAMICO DB CALDERAZZO F ENGLERT U MARCHETTI F HERBERICH GE PASQUALETTI N RAMELLO S
Citation
F. Bagnoli et al., NEW PREPARATIVE ACCESS TO AND THE CRYSTAL AND MOLECULAR-STRUCTURES OFCIS-[PTCL2(CO)(2)], Journal of the Chemical Society. Dalton transactions, (23), 1996, pp. 4317-4318
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
23
Year of publication
1996
Pages
4317 - 4318
Database
ISI
SICI code
0300-9246(1996):23<4317:NPATAT>2.0.ZU;2-V
Abstract
cis-Dicarbonyldichloroplatinum(II) has been found to be the thermodyna mically stable species arising from: (a) carbonylation of [NBu(4)](2)[ PtCl4] in the presence of AlCl3, (b) chlorination of [PtI2(CO)(2)]-[Pt 2I4(CO)(2)] with SO2Cl2 under CO and (c) carbonylation of PtCl2; the c rystal and molecular structures of cis-[PtCl2(CO)(2)] showed a short C -O distance [average 1.115(7) Angstrom] and intermolecular Pt ... Pt a nd C ... Cl contacts of less than 3.4 Angstrom.