ON THE USE OF THE KINETIC METHOD FOR THE DETERMINATION OF PROTON AFFINITIES BY FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE MASS-SPECTROMETRY

Citation
M. Decouzon et al., ON THE USE OF THE KINETIC METHOD FOR THE DETERMINATION OF PROTON AFFINITIES BY FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE MASS-SPECTROMETRY, Rapid communications in mass spectrometry, 10(2), 1996, pp. 242-245
Citations number
49
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
ISSN journal
09514198
Volume
10
Issue
2
Year of publication
1996
Pages
242 - 245
Database
ISI
SICI code
0951-4198(1996)10:2<242:OTUOTK>2.0.ZU;2-B
Abstract
The use in Fourier-transform ion cyclotron resonance (FTICR) mass spec trometry of the collision-induced dissociation of proton-bound dimers, the kinetic method or Cooks's method, is tested, This method is compa red with the proton-transfer equilibrium method, Good agreement betwee n the two methods is observed, Advantages and limitations of the FTICR kinetic method are briefly discussed.