REACTIONS OF ALPHA-TRIMETHYLSILYLVINYL CARBANIONS WITH CARBOXYLIC-ACID DERIVATIVES - THE RELATIONSHIP BETWEEN PRODUCT DISTRIBUTION AND SUBSTRATE REACTIVITY
Ar. Bassindale et al., REACTIONS OF ALPHA-TRIMETHYLSILYLVINYL CARBANIONS WITH CARBOXYLIC-ACID DERIVATIVES - THE RELATIONSHIP BETWEEN PRODUCT DISTRIBUTION AND SUBSTRATE REACTIVITY, Journal of the Chemical Society. Perkin transactions. I, (4), 1996, pp. 327-331
The reaction between alpha-trimethylsilylvinyl carbanions and carboxyl
ic acid derivatives gives alpha,beta-unsaturated carbonyl compounds wh
ich, under the reaction conditions, undergo further conjugate addition
, Further reactions can also occur, depending upon the reactivities of
the enolates and of the carboxylic acid derivatives.