Hj. Sanchez et M. Rubio, CORRECTIONS TO THE X-RAY-FLUORESCENCE EQUATIONS CONSIDERING DOUBLE K-PHOTOIONIZATION, Journal of analytical atomic spectrometry, 11(2), 1996, pp. 123-126
Some of the most common multi-electron transition processes are descri
bed and the effects of a double K-photoionization are analysed. Some p
revious experimental results are summarized, and the fact that fundame
ntal parameters (such as absorption edge jump ratios) are changed thro
ugh double ionization is shown. Finally, a correction to the equations
for X-ray fluorescence intensity due to the effects of the double K-i
onization is proposed by the inclusion of a step-function in the emiss
ion factor used in fundamental parameters calculation.