ON THE MECHANISM OF SUCCINYL TRANSFER FROM ARYL ENOLSUCCINATES TO ENOLATES OF ARYLKETONES - ADDITION-ELIMINATION VS ALKOXIDE-ASSISTED RETRO-ENE REACTION

Authors
MURRAY WV TURCHI IJ BUSSOLARI JC
Citation
Wv. Murray et al., ON THE MECHANISM OF SUCCINYL TRANSFER FROM ARYL ENOLSUCCINATES TO ENOLATES OF ARYLKETONES - ADDITION-ELIMINATION VS ALKOXIDE-ASSISTED RETRO-ENE REACTION, Perkin transactions. 2, (12), 1996, pp. 2715-2717
Citations number
18
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
12
Year of publication
1996
Pages
2715 - 2717
Database
ISI
SICI code
0300-9580(1996):12<2715:OTMOST>2.0.ZU;2-2
Abstract
The mechanism of succinyl transfer from aryl enolsuccinates to the eno lates of aryl ketones has been studied by deuterium exchange experimen ts and semi-empirical calculations. The calculations indicate that dir ect elimination is favoured over the ene mechanism, The results of a d euterium labelling study were also inconsistent with the ene mechanism .