Pa. Berge et Jg. Berryman, REALIZABILITY OF NEGATIVE PORE COMPRESSIBILITY IN POROELASTIC COMPOSITES, Journal of applied mechanics, 62(4), 1995, pp. 1053-1062
For elastic materials containing fluid-saturated porosity, the pore co
mpressibility is a measure of the deformation of a unit pore volume in
response to a change in fluid pressure. Rather than being measured, t
his quantity has been routinely set equal to an effective solid compre
ssibility, since this equality is exact whenever a single solid compon
ent is present. However, we show that the pore compressibility and sol
id compressibility may be uncorrelated in general. In certain special
circumstances they do not even share the same sign. Although thermodyn
amic and mechanical stability constraints cause solid and drained-fram
e bulk moduli of a porous composite to be positive and bounded by comp
onent properties, the pore compressibility is unconstrained and, there
fore, can have negative values. For special realizable model materials
, the value of the pore compressibility can be found using an exact ex
pression valid for a composite made up of one fluid and two solid comp
onents, i.e., two porous components. In order to quantify how various
factors affect the sign and magnitude of the pore compressibility, por
e compressibilities were calculated for models that used two porous co
mponents having the microgeometry of an assemblage of concentric spher
es. This model implicitly assumes the pores are on a much smaller leng
th scale than the concentric spheres. Modeling results show that with
the stiffer porous material forming the outer shells of the concentric
spheres, the pore compressibility of such materials is negative when
solid component bulk moduli differ by at least a factor of 5, if in ad
dition, the porosities and drained frame moduli of the two porous comp
onents are relatively low. Negative pore compressibilities were found
for realizable models whose two porous constituents had the properties
of silicon nitride and either sandstone or clay. For models using com
binations of alumina and glass foam properties, pore compressibilities
were non-negative but smaller than the compressibilities of the solid
components.