DETERMINATION OF INTENSITIES OF THE B-1-P I(U)-]X(1)SIGMA(-2 BY DENSITOMETRY ON PHOTOGRAPHIC PLATE - COMPARISON WITH THEORETICAL RESULTS AND EXPERIMENTAL RESULTS OBTAINED FROM PHOTOELECTRIC DEVICES()(G) BAND SYSTEM OF NA)

Citation
Jml. Poyato et al., DETERMINATION OF INTENSITIES OF THE B-1-P I(U)-]X(1)SIGMA(-2 BY DENSITOMETRY ON PHOTOGRAPHIC PLATE - COMPARISON WITH THEORETICAL RESULTS AND EXPERIMENTAL RESULTS OBTAINED FROM PHOTOELECTRIC DEVICES()(G) BAND SYSTEM OF NA), Anales de quimica, 91(7-8), 1995, pp. 496-501
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ISSN journal
11302283
Volume
91
Issue
7-8
Year of publication
1995
Pages
496 - 501
Database
ISI
SICI code
1130-2283(1995)91:7-8<496:DOIOTB>2.0.ZU;2-R
Abstract
The photoelectric recording of the spectra is the usual method for det ermining fluorescence intensities. This, however, requires the previou s calibration of the response of the photoelectric device to correct t he intensity of the primary spectra. For this correction a lamp with a well known spectral irradiance is normally used. In this work a proce dure for obtaining calibrated experimental intensities on photographic plate is described. This procedure is based on the sensitometric prop erties of photographic material. A comparison between radiative transi tion probabilities (theoretical values) obtained in this work and our experimental intensity values is shown for the most intense fluorescen ce series of a sample of sodium vapor, induced by 4765 and 4880 Angstr om argon-ion laser lines. Also this comparison is made with corrected experimental values obtained by using photoelectrical redording. In bo th cases, a good agreement with their corresponding theoretical terms is observed.