DETERMINATION OF INTENSITIES OF THE B-1-P I(U)-]X(1)SIGMA(-2 BY DENSITOMETRY ON PHOTOGRAPHIC PLATE - COMPARISON WITH THEORETICAL RESULTS AND EXPERIMENTAL RESULTS OBTAINED FROM PHOTOELECTRIC DEVICES()(G) BAND SYSTEM OF NA)
Jml. Poyato et al., DETERMINATION OF INTENSITIES OF THE B-1-P I(U)-]X(1)SIGMA(-2 BY DENSITOMETRY ON PHOTOGRAPHIC PLATE - COMPARISON WITH THEORETICAL RESULTS AND EXPERIMENTAL RESULTS OBTAINED FROM PHOTOELECTRIC DEVICES()(G) BAND SYSTEM OF NA), Anales de quimica, 91(7-8), 1995, pp. 496-501
The photoelectric recording of the spectra is the usual method for det
ermining fluorescence intensities. This, however, requires the previou
s calibration of the response of the photoelectric device to correct t
he intensity of the primary spectra. For this correction a lamp with a
well known spectral irradiance is normally used. In this work a proce
dure for obtaining calibrated experimental intensities on photographic
plate is described. This procedure is based on the sensitometric prop
erties of photographic material. A comparison between radiative transi
tion probabilities (theoretical values) obtained in this work and our
experimental intensity values is shown for the most intense fluorescen
ce series of a sample of sodium vapor, induced by 4765 and 4880 Angstr
om argon-ion laser lines. Also this comparison is made with corrected
experimental values obtained by using photoelectrical redording. In bo
th cases, a good agreement with their corresponding theoretical terms
is observed.