THE ROLE OF SILICON-OXYGEN INTERACTIONS IN DETERMINING THE STEREOCHEMICAL OUTCOME OF THE PETERSON REACTION

Authors
BASSINDALE AR ELLIS RJ TAYLOR PG
Citation
Ar. Bassindale et al., THE ROLE OF SILICON-OXYGEN INTERACTIONS IN DETERMINING THE STEREOCHEMICAL OUTCOME OF THE PETERSON REACTION, Journal of chemical research. Synopses, (1), 1996, pp. 34-35
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
1
Year of publication
1996
Pages
34 - 35
Database
ISI
SICI code
0308-2342(1996):1<34:TROSII>2.0.ZU;2-D
Abstract
The electronic effect of substituents on a benzene ring on the stereoc hemical outcome of the reaction of an alpha-triarylsilyl carbanion wit h an aldehyde is examined: the results can be interpreted in terms of the mode of approach of the carbanion towards the prochiral aldehyde, taking into account a variable oxygen-silicon interaction.