A ROUTE TO DIHYDRO[2]BENZOOXEPINO[4,5-C]PYRIDINES AND DIHYDROTHIENO[D][2]BENZOOXEPINES VIA THE 1.7-ELECTROCYCLIZATION OF CARBONYL YLIDES

Authors
OSHEA DF SHARP JT
Citation
Df. Oshea et Jt. Sharp, A ROUTE TO DIHYDRO[2]BENZOOXEPINO[4,5-C]PYRIDINES AND DIHYDROTHIENO[D][2]BENZOOXEPINES VIA THE 1.7-ELECTROCYCLIZATION OF CARBONYL YLIDES, Journal of the Chemical Society. Perkin transactions. I, (6), 1996, pp. 515-518
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
6
Year of publication
1996
Pages
515 - 518
Database
ISI
SICI code
0300-922X(1996):6<515:ARTDAD>2.0.ZU;2-2
Abstract
The cyclisation of diene-conjugated carbonyl ylides of the general typ e 2, in which the alpha,beta;gamma,delta diene function is formed by a benzene ring and either a thiophene or pyridine ring provides a new r oute to some hetero-fused dihydrobenzooxepines. The oxirane precursors for the carbonyl ylides were synthesised in a two-step scheme from re adily available reactants.