ELECTROCHEMICAL-BEHAVIOR OF CARBON ELECTRODES IN SOME ELECTROLYTE-SOLUTIONS

The electrochemical properties of coke and natural graphite in some el ectrolyte solutions containing diethylcarbonate (DEC) are studied. It is found that natural graphite exhibits an excellent performance, such as high discharge capacity (370 mAh(-1) g), when a mixed solvent comp osed of ethylene carbonate (EC) and DEC is used. The charge/discharge characteristics of the coke electrode are not influenced by the specie s of the electrolyte solution, but those of the natural graphite elect rode are very much influenced by the species of the electrolyte soluti on. It is confirmed that there are three patterns in the behaviour of the graphite electrode in the electrolyte solutions tested in this inv estigation. In the first pattern, natural graphite can be charged to C 6Li and then discharged. In the second pattern, the charging and disch arging of the natural graphite electrode is impossible and destruction of the natural graphite crystal structure is observed. In the third p attern, lithium is intercalated into the graphite layer but the de-int ercalation of lithium does not take place.