A DRASTIC EFFECT OF HALIDE ANIONS ON THE NUCLEOPHILIC-SUBSTITUTION OF1-PHENYLBENZO[B]THIOPHENIUM SALTS

Authors
KITAMURA T SODA SI MORIZANE K FUJIWARA Y TANIGUCHI H
Citation
T. Kitamura et al., A DRASTIC EFFECT OF HALIDE ANIONS ON THE NUCLEOPHILIC-SUBSTITUTION OF1-PHENYLBENZO[B]THIOPHENIUM SALTS, Perkin transactions. 2, (4), 1996, pp. 473-474
Citations number
25
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
4
Year of publication
1996
Pages
473 - 474
Database
ISI
SICI code
0300-9580(1996):4<473:ADEOHA>2.0.ZU;2-R
Abstract
Nucleophilic substitution of 1,2,3-triarylbenzo[b]thiophenium salts wi th halide anions (Cl- and Br-) has been found to yield 2,3-diarylbenzo [b] thiophenes, halobenzenes and -diaryl-1-halo-2-[2-(phenylsulfanyl)p henyl]ethenes and especially the reaction with iodide anion gives only 2,3-diarylbenzo[b]thiophenes and iodobenzene, indicating that halide anions behave quite differently from the reaction with alkoxide anions reported previously.