SPECTROSCOPIC TITRATION OF [RE-4(MU(3)-H)(4)(CO)(12)] WITH CHLORIDE-IONS - AN ELECTRON-PRECISE TETRANUCLEAR CLUSTER AS INTERMEDIATE IN THE TRANSFORMATION OF A TETRANUCLEAR UNSATURATED CLUSTER INTO TRINUCLEAR UNSATURATED ANIONS

Authors
BERINGHELLI T DALFONSO G GARAVAGLIA MG
Citation
T. Beringhelli et al., SPECTROSCOPIC TITRATION OF [RE-4(MU(3)-H)(4)(CO)(12)] WITH CHLORIDE-IONS - AN ELECTRON-PRECISE TETRANUCLEAR CLUSTER AS INTERMEDIATE IN THE TRANSFORMATION OF A TETRANUCLEAR UNSATURATED CLUSTER INTO TRINUCLEAR UNSATURATED ANIONS, Journal of the Chemical Society. Dalton transactions, (8), 1996, pp. 1771-1773
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
8
Year of publication
1996
Pages
1771 - 1773
Database
ISI
SICI code
0300-9246(1996):8<1771:STO[WC>2.0.ZU;2-B
Abstract
The unsaturated tetrahedral cluster [Re-4(mu(3)-H)(4)(CO)(12)] easily added halide ions giving [Re(4)H(4)X(CO)(12)](-) anions, which in the presence of even poor donor species underwent fragmentation to unsatur ated triangular cluster anions.