KINETICS OF ISOPENTANE DEHYDROGENATION OVER PLATINUM-ALUMINA CATALYSTS IN THE PRESENCE OF HYDROGEN AND WATER-VAPOR

Authors
LOC LC GAIDAI NA KIPERMAN SL THOANG HS
Citation
Lc. Loc et al., KINETICS OF ISOPENTANE DEHYDROGENATION OVER PLATINUM-ALUMINA CATALYSTS IN THE PRESENCE OF HYDROGEN AND WATER-VAPOR, Kinetics and catalysis, 37(6), 1996, pp. 797-801
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
37
Issue
6
Year of publication
1996
Pages
797 - 801
Database
ISI
SICI code
0023-1584(1996)37:6<797:KOIDOP>2.0.ZU;2-M
Abstract
The kinetics of isopentane dehydrogenation into isoamylenes and isopre ne in the presence of hydrogen and water vapor over potassium-, tin-, and indium-promoted platinum-alumina catalysts were studied. The rate equation was derived. Tin and indium promotion was shown to have no ef fect on the reaction kinetics and to increase the reaction rate and th e selectivity of the catalysts. The retardation of the reaction by iso amylenes and isoprene tends to decrease, while the inhibition effect c aused by water vapor aggravates.