HETERONULCEAR PT-PD, PT2CU AND PT2NI COMPLEXES WITH BRIDGING ACETAMIDATE - CRYSTAL-STRUCTURES AND SPECTROSCOPIC STUDIES

Authors
ERXLEBEN A ALBINATI A LIPPERT B
Citation
A. Erxleben et al., HETERONULCEAR PT-PD, PT2CU AND PT2NI COMPLEXES WITH BRIDGING ACETAMIDATE - CRYSTAL-STRUCTURES AND SPECTROSCOPIC STUDIES, Journal of the Chemical Society. Dalton transactions, (9), 1996, pp. 1823-1828
Citations number
52
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
9
Year of publication
1996
Pages
1823 - 1828
Database
ISI
SICI code
0300-9246(1996):9<1823:HPPAPC>2.0.ZU;2-J
Abstract
The reaction of trans- and cis-[Pt(NH3)(2)(NHCOMe-N)(2)] 1 and 2 with heterometals [(en)Pd-II (en = ethane-1,2-diamine), Cu2+ or Ni2+] has b een investigated. Dinuclear compounds of stoichiometry PtML(2) and tri nuclear Pt(2)ML(4) complexes with the heterometals co-ordinating throu gh the amide oxygens have been characterised and studied in solution. The crystal structures of [(NH3)(2)Pt(NHCOMe)(2)Pd(en)][ClO4](1.5)[NO3 ](0.5) 3, cis-[{Pt(NH3)(2)(NHCOMe)(2)}Cu-2][ClO4](2) 4 and cis-[{Pt(NH 3)(2)(NHCOMe)(2)}Ni-2][ClO4](2) 5 have been determined.