Jb. Shi et Hj. Tsao, SYNTHESIS AND MAGNETISM OF (HG0.7BI0.3)SR(2)RCU(2)O(6+DELTA) (R=PR, ND, AND GD) SYSTEM, Zhongguo wuli xuekan, 34(2), 1996, pp. 259-262
The problems of making phase-pure (Hg0.7Bi0.3)Sr(2)RCu(2)O(6+delta) sy
stem, with R = Pr, Nd, and Gd, are discussed in detail. Complete subst
itution of these three rare earths at the Ca site is realized in this
system. We identify the phase responsible for the magnetism to be simi
lar to that of TlBa2CaCu2O6+delta (so-called 1212 phase) with a space
group of P4/mmm and lattice constants of a similar to 3.8 Angstrom and
c similar to 12 Angstrom. Magnetic-susceptibility (chi) measurements
on these samples give an effective moment close to +3 for Gd, lower th
an +3 for Nd, but intermediate between those of +3 and +4 for Pr. No a
nomalous rare-earth (Pr, Nd, Gd) antiferromagnetic orderings were obse
rved down to 5 K.