ELECTROCHEMISTRY OF HYDRIDE-FORMING INTER METALLIC COMPOUNDS AND ALLOYS

Citation
Oa. Petrii et al., ELECTROCHEMISTRY OF HYDRIDE-FORMING INTER METALLIC COMPOUNDS AND ALLOYS, Uspehi himii, 65(3), 1996, pp. 195-210
Citations number
156
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00421308
Volume
65
Issue
3
Year of publication
1996
Pages
195 - 210
Database
ISI
SICI code
0042-1308(1996)65:3<195:EOHIMC>2.0.ZU;2-8
Abstract
The present review deals with studies published over recent 15 years a nd devoted to the electrochemistry of hydride-forming intermetallic co mpounds (IMC) and alloys. Data on the discharge capacity and the stabi lity at potential cycling of electrode materials based on IMC and AB, AB(2), AB(3), and AB(5) types alloys and their substituted derivatives are classified and generalised. The problems concerning the optimisat ion of the elemental composition of IMC and alloys, their production a nd activation, as well as the factors causing degradation of electrode s manufactured on their basis are discussed. The mathematical models s uggested for describing the processes of discharge and degradation of metal-hydride electrodes are analyzed.