TRANSFORMATION KINETICS IN ONE-DIMENSIONAL PROCESSES WITH CONTINUOUS NUCLEATION - THE EFFECT OF SHIELDING

Citation
Mc. Weinberg et Dp. Birnie, TRANSFORMATION KINETICS IN ONE-DIMENSIONAL PROCESSES WITH CONTINUOUS NUCLEATION - THE EFFECT OF SHIELDING, The Journal of chemical physics, 105(12), 1996, pp. 5138-5144
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
105
Issue
12
Year of publication
1996
Pages
5138 - 5144
Database
ISI
SICI code
0021-9606(1996)105:12<5138:TKIOPW>2.0.ZU;2-T
Abstract
A derivation is presented for the fraction of material transformed as a function of time, X(t), for one-dimensional phase transformations wh ich occur via continuous nucleation and growth and which produce aniso tropic particles. This derivation, which accounts for shielding effect s and does not assume site saturation, is the first such derivation gi ven for this type of problem. The analytical formulas which are found are evaluated in an approximate fashion for two different values of gr owth rate anisotropy. The results are compared with numerical simulati ons, and it is shown that the expressions derived are highly accurate. (C) 1996 American Institute of Physics.