STRUCTURAL RELAXATION IN VISCOUS GLYCEROL - COHERENT NEUTRON-SCATTERING

Citation
J. Wuttke et al., STRUCTURAL RELAXATION IN VISCOUS GLYCEROL - COHERENT NEUTRON-SCATTERING, The Journal of chemical physics, 105(12), 1996, pp. 5177-5182
Citations number
74
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
105
Issue
12
Year of publication
1996
Pages
5177 - 5182
Database
ISI
SICI code
0021-9606(1996)105:12<5177:SRIVG->2.0.ZU;2-B
Abstract
Structural relaxation in viscous glycerol has been followed from 5.9 p s to 3.7 ns by coherent neutron scattering around the structure factor maximum. In a 100 K interval, the line shape of the decay function sh ows no significant temperature dependence; the mean relaxation time sc ales accurately with viscosity. Interparticle correlations decay slowe r and with less stretching than self correlations at similar wave numb ers. (C) 1996 American Institute of Physics.