FEMTOSECOND REACTION DYNAMICS IN THE GAS-TO-LIQUID TRANSITION REGION - OBSERVATION OF A 3-PHASE DENSITY-DEPENDENCE

Authors
LIU QL WAN CZ ZEWAIL AH
Citation
Ql. Liu et al., FEMTOSECOND REACTION DYNAMICS IN THE GAS-TO-LIQUID TRANSITION REGION - OBSERVATION OF A 3-PHASE DENSITY-DEPENDENCE, The Journal of chemical physics, 105(12), 1996, pp. 5294-5297
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
105
Issue
12
Year of publication
1996
Pages
5294 - 5297
Database
ISI
SICI code
0021-9606(1996)105:12<5294:FRDITG>2.0.ZU;2-0
Abstract
We report the observation of a striking density dependence in the cohe rence dynamics of an elementary reaction, solute iodine in solvent rar e gases (density from 0 to 50 mol/l). With the help of MD simulations, the time scales of slow and fast solvent-force fluctuations are resol ved and the underlying mechanism is revealed. (C) 1996 American Instit ute of Physics.