ACTION OF DITHIOPHOSPHORIC ACID TOWARDS SULFURATED ALKYNES IN PRESENCE OF TRANSITION-METAL-CATALYST

Authors
DODINCARNOT V STEPHAN B CURCI M MIELOSZYNSKI JL PAQUER D
Citation
V. Dodincarnot et al., ACTION OF DITHIOPHOSPHORIC ACID TOWARDS SULFURATED ALKYNES IN PRESENCE OF TRANSITION-METAL-CATALYST, Phosphorus, sulfur and silicon and the related elements, 108(1-4), 1996, pp. 1-5
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
108
Issue
1-4
Year of publication
1996
Pages
1 - 5
Database
ISI
SICI code
1042-6507(1996)108:1-4<1:AODATS>2.0.ZU;2-4
Abstract
The reactivity of sulfurated substituted alkynes with dithiophosphoric acid has been investigated. Depending on the catalyst (Pd, Rh, Ni) an d the solvent (benzene or THF) two types of alkenes can be isolated: Z -C(Me)=CH-R and/or Z-C(R)=CH-Me. The selectivity of this reaction was studied. C-13 and P-31 NMR of these new sulfurated alkenes were report ed.