HETEROCYCLES AS LIGANDS .22. 2-CHALCOGENO IMIDAZOLINES AS LIGANDS IN PENTACARBONYLMETAL COMPLEXES

Authors
KUHN N FAWZI R KRATZ T STEIMANN M
Citation
N. Kuhn et al., HETEROCYCLES AS LIGANDS .22. 2-CHALCOGENO IMIDAZOLINES AS LIGANDS IN PENTACARBONYLMETAL COMPLEXES, Phosphorus, sulfur and silicon and the related elements, 108(1-4), 1996, pp. 107-119
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
108
Issue
1-4
Year of publication
1996
Pages
107 - 119
Database
ISI
SICI code
1042-6507(1996)108:1-4<107:HAL.2I>2.0.ZU;2-3
Abstract
The chalcogenoimidazoline complexes NR-CMe-CMe-NR-C=X . M(CO)(5) (VIII -XI; R = Me, iso-Pr; X = S, Se, Te; M = Cr, Mo, W) are obtained from t he metal hexacarbonyls (M = Cr, Mo, W) and the chalcogenoimidazolines IV-VIL. ln these complexes the chalcogeno ligands exhibit strong donor properties according to the sequence Te > Se > S which is demonstrate d by n. m. r. and i. r. data. The X-ray structures of N(iso-Pr)-CMe-CM e-N(iso-Pr)-C=X . Cr(CO)(5)(X = S; Se; VIIIa, IXa) are reported.