REACTIONS OF THIOXO COMPOUNDS WITH N-CHLO ROAMIDES .6. THIOQUINOLONES, DIHYDROTHIAZOLETHIONES AND DIHYDROISOTHIAZOLETHIONES WITH SODIUM N-CHLOROBENZENESULFONAMIDES

Citation
F. Boberg et al., REACTIONS OF THIOXO COMPOUNDS WITH N-CHLO ROAMIDES .6. THIOQUINOLONES, DIHYDROTHIAZOLETHIONES AND DIHYDROISOTHIAZOLETHIONES WITH SODIUM N-CHLOROBENZENESULFONAMIDES, Phosphorus, sulfur and silicon and the related elements, 108(1-4), 1996, pp. 203-220
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
108
Issue
1-4
Year of publication
1996
Pages
203 - 220
Database
ISI
SICI code
1042-6507(1996)108:1-4<203:ROTCWN>2.0.ZU;2-A
Abstract
Reactions of sodium N-chlorobenzenesulfonamides (1a-1e) with N-alkylth ioxo-dihydroderivates of the following heterocycles (A) have been stud ied: quinoline, isoquinoline, thiazole, isothiazole, benzothiazole, 1, 2-benzisothiazole, 2,1-benzisothiazole, 1,2-benzisothiazole 1,1-dioxid e. Reaction products are -arylsulfonyl-S-(dihydroheteroarylidene)sulfi mides (B), ,N'-bis(arylsulfonyl)heteroareniumsulfinamidinates (C) and N-(dihydroheteroarylidene)arensulfonamides (D). Oxidation of some sulf imides (B) gives N-(arylsulfonyl)heteroareniumsulfonamidates (E). The situation of bonding is discussed for B-E.