Jl. Luche, SONOCHEMICAL ACTIVATION IN ORGANIC-SYNTHESIS .2., Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 323(5), 1996, pp. 337-354
Biphasic sonochemical reactions of interest for synthetic purposes wil
l be exposed in this second part. When solids are present, a consisten
t interpretation is difficult due to the superposition of several effe
cts-mechanical, tribochemical. chemical-but their synthetic use is hig
hly versatile. In some examples, sonication acts as a Physical phase t
ransfer agent. Many organometallic reactions have been studied under s
onication, and the preparation step is greatly improved, frequently pe
rmitting one-step processes. The unexpected possibility to perform org
anometallic chemistry in aqueous media constitutes an important achiev
ement in sonochemistry.