SONOCHEMICAL ACTIVATION IN ORGANIC-SYNTHESIS .2.

Authors
Citation
Jl. Luche, SONOCHEMICAL ACTIVATION IN ORGANIC-SYNTHESIS .2., Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 323(5), 1996, pp. 337-354
Citations number
111
Categorie Soggetti
Multidisciplinary Sciences
ISSN journal
12518069
Volume
323
Issue
5
Year of publication
1996
Pages
337 - 354
Database
ISI
SICI code
1251-8069(1996)323:5<337:SAIO.>2.0.ZU;2-Y
Abstract
Biphasic sonochemical reactions of interest for synthetic purposes wil l be exposed in this second part. When solids are present, a consisten t interpretation is difficult due to the superposition of several effe cts-mechanical, tribochemical. chemical-but their synthetic use is hig hly versatile. In some examples, sonication acts as a Physical phase t ransfer agent. Many organometallic reactions have been studied under s onication, and the preparation step is greatly improved, frequently pe rmitting one-step processes. The unexpected possibility to perform org anometallic chemistry in aqueous media constitutes an important achiev ement in sonochemistry.