The growth of beta-SiC films on Si(100) substrates using C2H2 gas and
Si solid sources in a molecular beam epitaxy system has been investiga
ted. Different C2H2 and Si fluxes as well as different substrate tempe
ratures have been used. The growth was performed at two steps: the ini
tial optimal carbonisation step followed by the MBE growth with simult
aneous supply of Si molecular and C2H2 gas beams. The films were analy
sed using reflected high-energy electron diffraction, scanning electro
n microscopy, transmission electron microscopy. atomic force microscop
y and Fourier transform infrared spectroscopy. Thin (< 0.1 mu m) singl
e crystalline SiC was grown at 980 degrees C while 850 degrees C was s
ufficient for the carbonisation of the Si surface, Films thicker than
0.1 pm are partially polycrystalline.