STEREOSELECTIVE SYNTHESIS OF (E)-VINYLIC SELENIDES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS

Authors
Citation
X. Huang et Ls. Zhu, STEREOSELECTIVE SYNTHESIS OF (E)-VINYLIC SELENIDES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS, Journal of organometallic chemistry, 523(1), 1996, pp. 9-11
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
523
Issue
1
Year of publication
1996
Pages
9 - 11
Database
ISI
SICI code
0022-328X(1996)523:1<9:SSO(SB>2.0.ZU;2-D
Abstract
Hydrozirconation of arylselenoethynes gives zirconium (IV) complexes 3 , which are cross-coupled with aryl halides in the presence of tetraki s (triphenylphosphine) palladium catalyst to afford (E)-vinylic seleni des 5 in high yield.