A NEW PATHWAY FOR THE SYNTHESIS OF 1,3-DIOXA-6-AZA-2-GERMACYCLOOCTANES - MOLECULAR-STRUCTURE OF IENYL)-6-METHYL-1,3-DIOXA-6-AZA-2-GERMACYCLOOCTANE

Authors
LUKEVICS E BELYAKOV S PUDOVA O
Citation
E. Lukevics et al., A NEW PATHWAY FOR THE SYNTHESIS OF 1,3-DIOXA-6-AZA-2-GERMACYCLOOCTANES - MOLECULAR-STRUCTURE OF IENYL)-6-METHYL-1,3-DIOXA-6-AZA-2-GERMACYCLOOCTANE, Journal of organometallic chemistry, 523(1), 1996, pp. 41-45
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
523
Issue
1
Year of publication
1996
Pages
41 - 45
Database
ISI
SICI code
0022-328X(1996)523:1<41:ANPFTS>2.0.ZU;2-X
Abstract
A novel reaction pathway has been applied for the synthesis of 1,3-dio xa-6-aza-2-germacyclooctanes. Compounds of this type were obtained by the dehydrocondensation of di(2-thienyl)germane and diethanolamines wi thout a catalyst. The molecular structure of -di(2-thienyl)-6-methyl-1 ,3-dioxa-5-azacyclooctane has been determined by X-ray diffraction stu dy. The interatomic N --> Ge distance of 2.446 Angstrom indicates the presence of a weak transannular bond.