PALLADIUM-ASSISTED INTRAMOLECULAR FORMATION OF N-HETEROCYCLES BY SP(2) N-NUCLEOPHILIC-ATTACK ON ETA(3)-ALKYL-PD COMPLEXES GENERATED BY ALLENE INSERTION INTO SIGMA-PD-C BOND

Authors
CHENGEBROYEN J PFEFFER M SIRLIN C
Citation
J. Chengebroyen et al., PALLADIUM-ASSISTED INTRAMOLECULAR FORMATION OF N-HETEROCYCLES BY SP(2) N-NUCLEOPHILIC-ATTACK ON ETA(3)-ALKYL-PD COMPLEXES GENERATED BY ALLENE INSERTION INTO SIGMA-PD-C BOND, Tetrahedron letters, 37(40), 1996, pp. 7263-7266
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
40
Year of publication
1996
Pages
7263 - 7266
Database
ISI
SICI code
0040-4039(1996)37:40<7263:PIFONB>2.0.ZU;2-L
Abstract
1,1-dimethylallene inserts into the sigma Pd-C bond of a series of cyc lopalladated pyridine derivatives leading to stable or unstable eta(3) -allyl-Pd complexes. The demetallation of the latter leads to pyridini um derivatives with good yields. Copyright (C) 1996 Elsevier Science L td