M. Brinkmann et al., RESIDUAL RESISTIVITY AND OXYGEN STOICHIOMETRY IN PR2-XCEXCUO4-CRYSTALS(DELTA SINGLE), Physica. C, Superconductivity, 269(1-2), 1996, pp. 76-82
Using an improved high-temperature annealing procedure we homogeneousl
y vary the oxygen content of Pr2-xCexCuO4+delta single crystals and ch
ange the superconducting transition temperature in small steps. Minute
changes of the oxygen concentration delta give rise to a strong incre
ase of the residual resistivity but leave the Hall and the Seebeck coe
fficient nearly unchanged. A strong correlation of the change of the r
esidual resistivity and the change of T-c suggests that the point-defe
ct scattering rate on oxygen interstitials or oxygen vacancies is an i
mportant parameter determining T-c in the electron-doped high-T-c syst
ems.