H. Murakami et al., SUPERCONDUCTIVITY AND TRANSPORT-PROPERTIES OF NARROW-GAP SEMICONDUCTOR PB(TL)TE FILM BY HWE GROWTH, Physica. C, Superconductivity, 269(1-2), 1996, pp. 83-91
The IV-VI semiconductor PbTe doped with a small amount of Tl shows sup
erconductivity of T(c max)similar to 1.4 K in spite of the small hole
carrier densities of p similar to 10(20) cm(-3). The superconducting g
enerating mechanism has received much attention from the viewpoint of
carrier resonance scattering with a Tl quasi-localized state. In order
to investigate the superconductivity on well-defined film samples, we
prepared high-quality Pb(Tl)Te films by the HWE method, and carried o
ut the observation of superconductivity and electrical-transport prope
rties. Furthermore, in the experiment with the coordinated system of P
b(Tl,Na)Te film, the results show for the first time the possible exis
tence of two quasi-localized states of Tl causing strong scattering of
carriers accompanied by reduction in Hall mobility mu, which play an
important role in the superconductivity of this Pb(Tl)Te system.