N,N-DIMETHYLACRYLAMIDE-TRIFLIC ANHYDRIDE COMPLEX AS A NOVEL BIFUNCTIONAL ELECTROPHILE IN REACTION WITH ELECTRON-RICH AROMATICS

Authors
NENAJDENKO VG BARAZNENOK IL BALENKOVA ES
Citation
Vg. Nenajdenko et al., N,N-DIMETHYLACRYLAMIDE-TRIFLIC ANHYDRIDE COMPLEX AS A NOVEL BIFUNCTIONAL ELECTROPHILE IN REACTION WITH ELECTRON-RICH AROMATICS, Tetrahedron, 52(40), 1996, pp. 12993-13006
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
40
Year of publication
1996
Pages
12993 - 13006
Database
ISI
SICI code
0040-4020(1996)52:40<12993:NACAAN>2.0.ZU;2-I
Abstract
The reaction of N,N-dimethylacrylamide/trifluoromethanesulfonic anhydr ide complex with alkoxybenzenes followed by hydrolysis leads to the co rresponding indan-1-ones and 1,3-diarylpropan-1-ones. Substituted naph thalenes yield dihydrophenalen-1-ones. Fused ring aromatics afford aro matic amines. Copyright (C) 1996 Elsevier Science Ltd