CONVERSIONS OF HYDROCARBONS TREATED WITH NEODYMIUM METAL UNDER THE CONDITIONS OF MECHANOCHEMICAL ACTIVATION AT ROOM-TEMPERATURE

Authors
DOLGOPLOSK BA YAKOVLEV VA TINYAKOVA EI GOLSHTEIN SB BONDARENKO GN
Citation
Ba. Dolgoplosk et al., CONVERSIONS OF HYDROCARBONS TREATED WITH NEODYMIUM METAL UNDER THE CONDITIONS OF MECHANOCHEMICAL ACTIVATION AT ROOM-TEMPERATURE, Russian chemical bulletin, 45(6), 1996, pp. 1316-1320
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
6
Year of publication
1996
Pages
1316 - 1320
Database
ISI
SICI code
1066-5285(1996)45:6<1316:COHTWN>2.0.ZU;2-N
Abstract
The conversions of cyclohexene and 1,3- and 1,4-cyclohexadienes treate d with neodymium metal under the conditions of mechanochemical activat ion at 20 degrees C have been studied. A complicated cycle of conversi ons, including isomerization, disproportionation, and polymerization, occurs under the reaction conditions. A mechanism for the conversion o f tile hydrocarbons involving organometallic intermediates is proposed .