ENERGY-TRANSFER IN LUMINESCENT COMPLEXES OF EU-III AND TB-III WITH HOMOPOLYMERS AND COPOLYMERS OF ACRYLIC-ACID AND ALKYL METHACRYLATES

Authors
MIROCHNIK AG PETROCHENKOVA NV KARASEV VE
Citation
Ag. Mirochnik et al., ENERGY-TRANSFER IN LUMINESCENT COMPLEXES OF EU-III AND TB-III WITH HOMOPOLYMERS AND COPOLYMERS OF ACRYLIC-ACID AND ALKYL METHACRYLATES, Russian chemical bulletin, 45(6), 1996, pp. 1356-1359
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
6
Year of publication
1996
Pages
1356 - 1359
Database
ISI
SICI code
1066-5285(1996)45:6<1356:EILCOE>2.0.ZU;2-Z
Abstract
The influence of the composition and structure of a macromolecular lig and on the efficiency of energy transfer in complexes of Eu-III and Tb -III with ligands based on acrylic acid has been studied. It has been found that a decrease in tile size of an alkyl group of methacrylic es ters and a low content of acrylic moieties of Eu-III complexes with co polymers increase the efficiency of Eu-III concentration quenching. In sertion of noncoordinative alkyl methacrylate into the polymeric chain results ill an increase in tile efficiency of energy transfer from Tb 3+ to Eu3+.