ANALYSIS OF CHIROPTICAL PROPERTIES OF PI-ALLYL COMPLEX [PD(BETA-PINENYL)CL](2)

Authors
KLYAGINA AP MISAILOVA TV GOLOVANEVA IF GUBIN SP
Citation
Ap. Klyagina et al., ANALYSIS OF CHIROPTICAL PROPERTIES OF PI-ALLYL COMPLEX [PD(BETA-PINENYL)CL](2), Russian chemical bulletin, 45(6), 1996, pp. 1487-1489
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
6
Year of publication
1996
Pages
1487 - 1489
Database
ISI
SICI code
1066-5285(1996)45:6<1487:AOCPOP>2.0.ZU;2-L
Abstract
Electronic absorption and circular dichroism spectra of the optically active [Pd(beta-pinenyl)Cl](2) complex (1) have been studied. The assi gnment of the bands in tile circular dichroism spectrum in the d-d-tra nsition region of complex 1 was made within tile framework of tile one -electron model of optical activity; this assignment is in agreement w ith tile literature data on the analysis of the absorption spectrum of [Pd(allyl)Cl](2). The (1R,2S,3S,5R) absolute configuration was sugges ted for the optical (+)(589)-isomer of 1 studied.